Hi,
People pickers can be used as triggers in SP2013, but if you are on SP2010 you can set up this function in the Custom JS:
/* Change "Level" to match you radio choice field name and "PeoplePicker" to match your people picker field name */
setInterval(function(){
var level = getFieldValue("Level"), ppArr;
if(level !== ""){
ppArr = getFieldValue("PeoplePicker");
if(ppArr.length === 0){
// Clear radio choice
setFieldValue("Level","");
}
}
},1000);
Hope this helps,
Alexander